One Direction as The Avengers
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Liam:
Captain America; loyal, kind, and just about as puppy-like as it's gonna get.
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Niall:
Thor; typical asgaardian appetite.
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Louis:
Black Widow; the ass matches and everything!
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Zayn:
Hawkeye; Casually corrupted for a while and still badass.
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Harry:
The Hulk; touch his curls (or Louis, for that matter) and HARRY SMASH.
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Simon:
Nick Fury; the movie man that put it all together.
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Tumblr:
Agent Phil Coulson; the undercover fangirl skills are obvious.